The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 58 of 178 (32%)
page 58 of 178 (32%)
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itself is found in California and Nevada, U.S.A., and also in Peru,
Ceylon, China, Persia, and Thibet. The commercial product is obtained from the native borax (known as "tincal") by dissolving in water and allowing the solution to crystallise. The Peruvian borax sometimes contains nitre. For testing the purity of refined borax the following simple tests will usually suffice. A solution of the borax is made containing 1 part of borax to 50 parts of water, and small portions of the solution are tested as follows: _Heavy metals_ (_lead_, _copper_, etc.).--On passing sulphuretted hydrogen into the solution, no coloration or precipitate should be produced. _Calcium Salts._--The solution should not give a precipitate with ammonium oxalate solution. _Carbonates._--The solution should not effervesce on addition of nitric or hydrochloric acid. _Chlorides._--No appreciable precipitate should be produced on addition of silver nitrate solution and nitric acid. _Sulphates._--No appreciable precipitate should be produced on adding hydrochloric acid and barium chloride. _Iron._--50 c.c. of the solution should not immediately be coloured blue by 0ยท5 c.c. of potassium ferrocyanide solution. _Soap._--Soap is a salt in the chemical sense, and this leads to a wider definition of the term "salt" or "saline" compound. Fats and oils, from which soaps are manufactured, are a kind of _quasi_ salts, composed of a fatty acid and a chemical constant, if I may use the term, in the shape of base, namely, glycerin. When these fats and oils, often called glycerides, are heated with alkali, soda, a true salt of the fatty acid and soda is formed, and this is the soap, whilst the glycerin remains behind in the "spent soap lye." Now glycerin is soluble in water containing dissolved salt (brine), whilst soap is insoluble, though soluble in pure water. The mixture of soap and glycerin produced from the fat and soda is therefore treated with brine, a process called |
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