The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 60 of 178 (33%)
page 60 of 178 (33%)
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alcohol and wood spirit. In many cases the alcoholic solutions show an
acid reaction. The resins are partly soluble in alkalis, with formation of a kind of alkali salts which we may call resin-soaps. Shellac is obtained from the resinous incrustation produced on the bark of the twigs and branches of various tropical trees by the puncture of the female "lac insect" (_Taccardia lacca_). The lac is removed from the twigs by "beating" in water; the woody matter floats to the surface, and the resin sinks to the bottom, and when removed forms what is known as "seed-lac." Formerly, the solution, which contains the colouring matter dissolved from the crude "stick-lac," was evaporated for recovery of the so-called "lac-dye," but the latter is no longer used technically. The seed-lac is bleached by boiling with sodium or potassium carbonate, alum, or borax, and then, if it is not pale enough, is further bleached by exposure to sunlight. It is now dried, melted, and mixed with a certain proportion of rosin or of orpiment (a sulphide of arsenic) according to the purpose for which it is desired. After further operations of melting and straining, the lac is melted and spread into thin sheets to form ordinary shellac, or is melted and dropped on to a smooth surface to form "button-lac." Ordinary shellac almost invariably contains some rosin, but good button-lac is free from this substance. The presence of 5 per cent. of rosin in shellac can be detected by dissolving in a little alcohol, pouring the solution into water, and drying the fine impalpable powder which separates. This powder is extracted with petroleum spirit, and the solution shaken with water containing a trace of copper acetate. If rosin be present, the petroleum spirit will be coloured emerald-green. Borax, soda crystals, and ammonia are all used to dissolve shellac, and it may be asked: Which of these is least injurious to wool? and why? How |
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