The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 63 of 178 (35%)
page 63 of 178 (35%)
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stiffen them at the same time and by the same process; and the third,
the one the importance of which I think English hat manufacturers have frequently overlooked, at least in the past, is to so proof and stiffen the hat-forms as to leave them in a suitable condition for the subsequent dyeing process. In proofing the felt, the fibres become varnished over with a kind of glaze which is insoluble in water, and this varnish or proof is but imperfectly removed from the ends of the fibres on the upper surface of the felt. The consequence is a too slight penetration of the dyestuff into the inner pores of the fibres; indeed, in the logwood black dyeing of such proofed felt a great deal of the colour becomes precipitated on the outside of the fibres--a kind of process of "smudging-on" of a black pigment taking place. The subsequent "greening" of the black hats after a short period of wear is simply due to the ease with which such badly fixed dye rubs off, washes off, or wears off, the brownish or yellowish substratum which gradually comes to light, causing a greenish shade to at length appear. If we examine under the microscope a pure unproofed fur fibre, its characteristic structure is quite visible. Examination of an unproofed fibre dyed with logwood black shows again the same characteristic structure with the dye inside the fibre, colouring it a beautiful bluish-grey tint, the inner cellular markings being black. A proofed fur fibre, on the other hand, when examined under the microscope, is seen to be covered with a kind of translucent glaze, which completely envelops it, and prevents the beautiful markings showing the scaly structure of the fibre from being seen. Finally, if we examine microscopically a proofed fibre which has been dyed, or which we have attempted to dye, with logwood black, we find that the fibre presents an appearance similar to that of rope which has been drawn through some black pigment or black mud, and then dried. It is quite plain that no lustrous appearance or good "finish" can be expected from such material. Now how did the Continental hat |
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