The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 71 of 178 (39%)
page 71 of 178 (39%)
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form sulphate of soda (Na_{2}SO_{4}), whilst the hydroxyl (OH) of the
caustic soda takes the position previously occupied by the SO_{4}. But this increase of basicity also means decrease of stability, for on boiling the solution, which now contains a basic sulphate of alumina, a precipitate is formed, a result which also follows if more caustic soda is added, production of still more basic salts or of hydrated alumina, Al_{2}(OH)_{6}, taking place in either case. _Mordanting or Fixing Acid (Phenolic) Colours._--But what has all this to do with mordanting? is possibly now the inquiry. So much as this, that only such unstable salts as I have just described, which decompose and yield precipitates by the action on them of alkalis, heat, the textile fibres themselves, or other agencies, are suitable to act as true mordants. Hence, generally, the sources or root substances of the best and most efficient mordants are the metals of high specific appetite or valency. I think we have now got a clue to the principle of mordants and also to the importance of a sound chemical knowledge in dealing most effectively with them, and I may tell you that the man who did most to elucidate the theory of mordanting is not a practical man in the general sense of the term, but a man of the highest scientific attainments and standing, namely, Professor Liechti, who, with his colleague Professor Suida, did probably more than any other man to clear up much that heretofore was cloudy in this region. We have seen that with aluminium sulphate, basic salts are precipitated, _i.e._ salts with such a predominance of appetite for acids, or such _quasi_-acids as phenolic substances, that if such bodies were present they would combine with the basic parts of those precipitated salts as soon as the latter were formed, and all would be precipitated together as one complex compound. Just such peculiar _quasi_-acid, or phenolic substances are Alizarin, and most of the natural adjective dyestuffs, the colouring |
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