The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 92 of 178 (51%)
page 92 of 178 (51%)
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ammonia, or spirits of hartshorn, is a compound of hydrogen with
nitrogen, three atoms of hydrogen being combined with one of nitrogen, thus, NH_{3}. An example of a hydrocarbon or compound of carbon and hydrogen, is marsh gas (methane) or firedamp, CH_{4}. Nitric acid, or _aqua fortis_, is a compound of nitrogen, oxygen, and hydrogen, one atom of the first to three of the second and one of the third--NO_{3}H. But this nitric acid question forces me on to a further statement, namely, we have in this formula or symbol, NO_{3}H, a twofold idea--first, that of the compound as a whole, an acid; and secondly, that it is formed from a substance without acid properties by the addition of water, H_{2}O, or, if we like, HOH. This substance contains the root or radical of the nitric acid, and is NO_{2}, which has the power of replacing one of the hydrogen atoms, or H, of water, and so we get, instead of HOH, NO_{2}OH, which is nitric acid. This is chemical replacement, and on such replacement depends our powers of building up not only colours, but many other useful and ornamental chemical structures. You have all heard the old-fashioned statement that "Nature abhors a vacuum." We had a very practical example of this when in our first lecture on water I brought an electric spark in contact with a mixture of free oxygen and hydrogen in a glass bulb. These gases at once united, three volumes of them condensing to two volumes, and these again to a minute particle of liquid water. A vacuum was left in that delicate glass bulb whilst the pressure of the atmosphere was crushing with a force of 15 lb. on the square inch on the outside of the bulb, and thus a violent crash was the result of Nature's abhorrence. There is such a kind of thing, though, and of a more subtle sort, which we might term a chemical vacuum, and it is the result of what we call chemical valency, which again might be defined as the specific chemical appetite of each substance. Let us now take the case of the production of an aniline colour, and let |
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