A Textbook of Assaying: For the Use of Those Connected with Mines. by John Jacob Beringer;Cornelius Beringer
page 34 of 691 (04%)
page 34 of 691 (04%)
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oxygen of the red lead is thus available for oxidising purposes. If this
oxidising power is prejudicial, it may be neutralised by mixing the red lead with 1 per cent. of charcoal. ~Glass~: broken beakers and flasks, cleaned, dried, and powdered will do. It should be free from lead. ~Fluor~: fluor-spar as free as possible from other minerals, powdered. It helps to flux phosphate of lime, &c., and infusible silicates. ~Lime~: should be fresh and powdered. It must not be slaked. Powdered white marble (carbonate of lime) will do; but nearly double the quantity must be taken. One part of lime produces the same effect as 1.8 parts of the carbonate of lime. ~Tartar~ and "black flux," are reducing agents as well as fluxes. The "black flux," which may be obtained by heating tartar, is a mixture of carbonate of potash and charcoal. REDUCING AGENTS.--The distinction between reducing agents and fluxes (too often ignored) is an important one. Fluxes yield slags; reducing agents give buttons of regulus or of metal. The action of a reducing agent is the separation of the oxygen or sulphur from the metal with which it is combined. For example, the mineral anglesite (lead sulphate) is a compound of lead, sulphur, and oxygen; by carefully heating it with charcoal the oxygen is taken away by the charcoal, and a regulus of lead sulphide remains. If the regulus be then fused with metallic iron the sulphur is removed by the iron, and metallic lead is left. The charcoal and the iron are reducing agents. But in defining a reducing agent as one which removes oxygen, or sulphur, from a metallic compound so as to |
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