A Textbook of Assaying: For the Use of Those Connected with Mines. by John Jacob Beringer;Cornelius Beringer
page 36 of 691 (05%)
page 36 of 691 (05%)
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finely divided carbon. Five parts of tartar should be used in the place
of one of charcoal. ~Anthracite~ or ~Culm~ is a kind of coal containing 90 per cent. or more of carbon. It gives off no inflammable gas. It is denser, and takes longer in burning, than charcoal. Its reducing effect is little inferior to that of charcoal. Almost any organic substance can be used as a reducing agent, but it is well not to select one which melts, swells up, or gives off much water and gas when heated in the furnace. ~Potassic Cyanide~ is an easily fusible and somewhat volatile salt, which, when fused, readily removes oxygen and sulphur from metallic compounds, and forms potassic cyanate or sulphocyanate as the case may be. Commercial samples vary much in purity; some contain less than 50 per cent. of the salt. For assaying, only the better qualities should be used. ~Iron~ is a de-sulphurising rather than a de-oxidising agent. Iron is used in the form of rods, 1/2-inch in diameter, or of nails, or of hoop iron. In the last case it should be thin enough to be bent without difficulty. Wrought iron crucibles are very useful in the processes required for making galena assays. _The chief oxidising agents (which are also de-sulphurisers)_ are the following:-- ~Nitre~, or Potassic Nitrate.--This salt fuses very easily to a watery liquid. It oxidises most combustible substances with deflagration, and thereby converts sulphides into sulphates, arsenides into arsenates, and most metals into oxides. In the presence of strong bases, such as soda, |
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