A Textbook of Assaying: For the Use of Those Connected with Mines. by John Jacob Beringer;Cornelius Beringer
page 55 of 691 (07%)
page 55 of 691 (07%)
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solution is next transferred to a dry "Winchester" bottle and labelled.
The label may be rendered permanent by waxing it. Standard solutions should not be kept in a place exposed to direct sunlight. Oxidising and reducing solutions, such as those of permanganate of potash, ferrous sulphate, iodine, hyposulphite of soda, &c., gradually weaken in strength; the solutions of other salts are more stable; while those of potassium bichromate and baric chloride are almost permanent. Solutions of potassium permanganate may be kept for a month or so without much change. The solutions of hyposulphite of soda and of iodine should be examined weekly. Ferrous sulphate solutions, if acidulated with sulphuric acid, may be depended on for two or three weeks without fresh standardising. Before filling the burette, the "Winchester" bottle should be well shaken and a portion of about 50 or 100 c.c. poured into a dry beaker or test-glass. Besides the standard solutions, which are required for titrating an assay, permanent solutions of the metal or acid of equivalent strength are very useful. When the finishing point of a titration has been overstepped (_i.e._, the assay has been "overdone"), a measured volume, say 5 or 10 c.c., of a solution containing the same metal may be added. The titration can then be continued, but more cautiously, and the value in "c.c." for the quantity added be deducted from the final reading. ~Standardising.~--Suppose the object is to standardise a solution of permanganate similar to that referred to above. A convenient quantity of iron (say 0.5 gram) would be weighed out, dissolved in dilute sulphuric acid, and the solution titrated. Suppose 49.6 c.c. of the permanganate solution are required, then 49.6 : 0.5 :: 100 : _x_ |
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