A Textbook of Assaying: For the Use of Those Connected with Mines. by John Jacob Beringer;Cornelius Beringer
page 82 of 691 (11%)
page 82 of 691 (11%)
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kept. It forms a comparatively unimportant class of salts (citrates). It
is used in the determination of phosphoric acid, chiefly for the purpose of preventing the precipitation of phosphates of iron and alumina by ammonia, and in a few similar cases. The commercial crystals are used; they should be free from sulphuric acid and leave no ash on ignition. ~Hydrochloric Acid~, HCl in water, (sp. gr. 1.16. It contains 32 per cent. of hydrogen chloride).--It is sometimes called "muriatic acid," and when impure, "spirit of salt." The acid solution should be colourless and free from arsenic, iron, and sulphuric acid. It forms an important family of salts, the chlorides. It is the best acid for dissolving metallic oxides and carbonates, and is always used by the assayer when oxidising agents are to be avoided. The acid is used without dilution when no directions are expressly given to dilute it. It has no action on the following metals: gold, platinum, arsenic, and mercury; it very slightly attacks antimony, bismuth, lead, silver, and copper. Tin is more soluble in it, but with difficulty; whilst iron, zinc, nickel, cobalt, cadmium, and aluminium easily dissolve with evolution of hydrogen and the formation of the lower chloride if the metal forms more than one class of salts. All the metallic oxides, except a few of the native and rarer oxides, are dissolved by it with the formation of chlorides of the metal and water. ~Dilute Hydrochloric Acid~ is made by diluting the strong acid with an equal volume of water. This is used for dissolving precipitates obtained in the general course of analysis and the more easily soluble metals. ~Hydrofluoric Acid, HF.~--A solution in water may be purchased in gutta-percha or lead bottles. It is of variable strength and doubtful purity. It must always be examined quantitatively for the residue left |
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