Scientific American Supplement, No. 365, December 30, 1882 by Various
page 11 of 115 (09%)
page 11 of 115 (09%)
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large quantities are present, a dark brown precipitate is formed. It was
soon found, however, that other substances than amyl alcohol produce brown colored solutions with silver nitrate; and Bouvier[1] observed that on adding potassium iodide to alcohol containing fusel oil, the solution is colored yellow, from the decomposition of the iodide. Subsequently Böttger[2] proved that potassium iodide is not decomposed by pure amyl alcohol, and that the decomposition is due to the presence of acids contained in fusel oil. More accurate results are obtained by using a very dilute solution of potassium permanganate, which is decomposed by amyl alcohol much more rapidly than by ethyl alcohol. [Footnote 1: Zeitschrift f. Anal. Chem. xi., 343.] [Footnote 2: Dingler's Polytech. Jour., ccxii., 516.] Depré[3] determines fusel oil by oxidizing a definite quantity of the alcohol in a closed vessel with potassium bichromate and sulphuric acid. after removal of excess of the oxidizing reagents, the organic acids are distilled, and, by repeated fractional distillation, the acetic acid is separated as completely as possible. The remaining acids are saturated with barium hydroxide, and the salts analyzed; a difference between the percentage of barium found and that of barium in barium acetate proves the presence of fusel oil, and the amount of difference gives some idea of its quantity. Betelli[4] dilutes 5 c.c. of the alcohol to be tested with 6 to 7 volumes of water, and adds 15 to 20 drops of chloroform and shakes thoroughly. If fusel oil is present, its odor may be detected by evaporating the chloroform; or, by treatment with sulphuric acid and sodium acetate, the ether is obtained, which can be readily recognized. Jorissen[5] tests for fusel oil by adding 10 drops of colorless aniline and 2 to 3 drops of hydrochloric acid to 10 c.c. of the alcohol. In the |
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