An Introduction to Chemical Science by Rufus Phillips Williams
page 60 of 262 (22%)
page 60 of 262 (22%)
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bonds. In organic chemistry the exceptions to this rule are very
numerous, and, in fact, we do not know that atoms have bonds at all; but we can best explain the phenomena by supposing them, and for a general statement we may say that there must be no free bonds. In binaries the bonds of each element must balance. 56. The Valence, Quantivalence, of an Element is its Combining Power Measured by Bonds.--H, having the least number of bonds, one, is taken as the unit. Valence has always to be taken into account in writing the symbol of a compound. It is often written above and after the elements [i.e. written like an exponent], as K^I, Mg^II. An element having a valence of one is a monad; of two, a dyad; three, a triad; four, tetrad; five, pentad; six, hexad, etc. It is also said to be monovalent, di- or bivalent, etc. This theory of bonds shows why an atom cannot exist alone. It would have free or unused bonds, and hence must combine with its fellow to form a molecule, in case of an element as well as in that of a compound. This is illustrated by these graphic symbols in which there are no free bonds: H-H, O=O, N[3-bond symbol]N, C[4-bond symbol]C. A graphic symbol shows apparent molecular structure. After all, how do we know that there are twice as many Cl atoms in the chloride of magnesium as in that of sodium? The compounds have been analyzed over and over again, and have been found to correspond to the symbols MgCl2 and NaCl. This will be better understood after studying the chapter on atomic weights. In writing the symbol for the union of H with O, if we take an atom of each, the bonds do not balance, H-=O, the former having one; |
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