Book-bot.com - read famous books online for free

An Introduction to Chemical Science by Rufus Phillips Williams
page 67 of 262 (25%)
battery (Physics, page 164), [References are made in this book to
Gage's Introduction to Physical Science.] and attach the terminal
wires to an electrolytic apparatus (Fig. 19) filled with water
made slightly acid with H2SO4. Construct a diagram of the
apparatus, marking the Zn in the liquid +, since it is positive,
and the C, or other element, -. Mark the electrode attached to
the Zn -, and that attached to the C +; positive electricity at
one end of a body commonly implies negative at the other.
Opposites attract, while like electricities repel each other.
These analogies will aid the memory. At the + electrode is the -
element of H2O, and at the - electrode the + element. Note, page
43, whether H or O is positive with reference to the other, and
write the symbol for each at the proper electrode. Compare the
diagram with the apparatus, to verify your conclusion. Why does
gas collect twice as fast at one electrode as at the other? What
does this prove of the composition of water? When filled, test
the gases in each tube, for O and H, with a burning stick.
Electrical analysis is called electrolysis.

If a solution of NaCl be electrolyzed, which element will go to
the + pole? Which, if the salt were K2SO4? Explain these
reactions in the electrolysis of that salt. K2SO4 = K2 + S03 + O.
SO4 is unstable, and breaks up into SO3 and O. Both K and SO3
have great affinity for water. K2 + 2 H2O = 2 KOH + H2. S03 + H2O
= H2SO4.

The base KOH would be found at the - electrode, and the acid
H2SO4 at the + electrode.

The positive portion, K, uniting with H2O forms a base; the
DigitalOcean Referral Badge