An Introduction to Chemical Science by Rufus Phillips Williams
page 69 of 262 (26%)
page 69 of 262 (26%)
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molecules. This law is the foundation of modern chemistry. A
cubic centimeter of O has as many molecules as a cubic centimeter of H, a liter of N the same number as a liter of steam, under similar conditions. Compare the number of molecules in 5 l. of N2O with that in 10 l. Cl. 7 cc. vapor of I to 6 cc. vapor of S. The half-molecules of two gases have, of course, the same relation to each other, and in elements the half-molecule is usually the atom. The molecular volumes--molecules and the surrounding space--of all gases must therefore be equal, as must the half-volumes. Notice that this law applies only to gases, not to liquids or solids. Let us apply it to the experiment for the electrolysis of water. In this we found twice as much H by volume as O. Evidently, then, steam has twice as many molecules of H as of O, and twice as many half-molecules, or atoms. If the molecule has one atom of O, it must have two of H, and the formula will be H2O. Suppose we reverse the process and synthesize steam, which can be done by passing an electric spark through a mixture of H and O in a eudiometer over mercury; we should need to take twice as much H as O. Now when 2 cc. of H combine thus with 1 cc. of O, only 2 cc.of steam are produced. Three volumes are condensed into two volumes, and of course three molecular volumes into two, three atomic volumes into two. This may be written as follows:-- H + H + O = H2O. This is a condensation of one-third. |
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