An Introduction to Chemical Science by Rufus Phillips Williams
page 71 of 262 (27%)
page 71 of 262 (27%)
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(4) In four volumes H2S how many volumes of each constituent?
(5) If three volumes of H be mixed with two volumes of S, so as to make H2S, how much will be formed? How much of either element will be left? An analysis of 2 cc. of ammonia gives 1 cc. N and 3 cc. H. The symbol must then be NH3, the reaction,-- NH3 = N + H + H + H. What condensation in the synthesis of NH3? In 12 cc. NH3 how many cubic centimeters of each element? In 2 1/2 cc? How much H by volume is required to combine with nine volumes of N? How many volumes of NH3 are produced? In elements that have not been weighed in the gaseous state, as C, the evidence of atomic volume is not direct, but we will assume it. Thus two volumes of marsh gas would separate into one of C and four of H. What is its symbol and supposed condensation? Two volumes of alcohol vapor resolve into two of C, six of H, and one of O. What is its symbol? its condensation? The symbol itself of a compound will usually show what its condensation is; e.g. HCl, HBr, HF, etc., have two atoms; hence there will be no shrinkage. In H2O, SO2, CO2, the molecule has three atoms condensed into the space of two, or one-third shrinkage. In NH3 four volumes are crowded into the space of two, a condensation of one-half. P, As, Hg, Zn, have exceptional atomic volumes. |
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