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An Introduction to Chemical Science by Rufus Phillips Williams
page 86 of 262 (32%)
the metal is pure, no action takes place. Into another tube put 6
cc. HCl and add a similar leaf. Heat this also. There should be
no action. Pour the contents of one t.t. into the other. Note the
effect. Which is stronger, one of the acids, or the combination
of the two? Note the odor. It is that of Cl. 3HCl + HNO3 = NOCl +
2H2O + Cl2. This reaction is approximate only. The strength is
owing to nascent chlorine, which unites with Au. Au + 3Cl =
AuCl3. If Pt be used, PtCl4 is produced. No other acid except
nitro-hydrochloric will dissolve Au or Pt; hence the ancients
called it aqua regia, or king of liquids. It must be made as
wanted, since it cannot be kept and retain its strength.

CHAPTER XIX.

SULPHURIC ACID.

90. Preparation.

Experiment 55.--Having fitted a cork with four or five
perforations to a large t.t., pass a d.t. from three of these to
three smaller t.t., leaving the others open to the air, as in
Figure 28. Into one t.t. put 5 cc. H2O, into another 5 g. Cu
turnings and 10 cc. H2SO4, into the third 5 g. Cu turnings and 10
cc. dilute HNO3, half water. Hang on a ring stand, and slowly
heat the tubes containing H2O and H2SO4. Notice the fumes that
pass into the large t.t.

Trace out and apply to Figure 28 these reactions:--

(1) Cu + 2 H2SO4 = CuSO4 + 2 H2O + SO2.
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