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An Introduction to Chemical Science by Rufus Phillips Williams
page 88 of 262 (33%)
reagent bottle in 10 cc. H2O in a clean t.t., and add 1 cc. BaCl2
solution. Look for any cloudiness. This is the characteristic
test for H2SO4 and soluble sulphates, and so delicate that one
drop in a liter of H2O can be detected. (4) Instead of H2SO4, try
a little Na2SO4 solution. (5) Put two or three drops of strong
H2SO4 on writing-paper, and evaporate, high over a flame, so as
not to burn the paper. Examine it when dry. (6) Put a stick into
a t.t. containing 2 cc. H2SO4, and note the effect. (7) Review
Experiment 5. (8) Into an e.d. pour 5 cc. H2O, and then 15 cc.
H2SO4. Stir it meantime with a small t.t. containing 2 or 3 cc.
NH4OH, and notice what takes place in the latter; also note the
heat of the e.d.

The effects of (5), (6), (7), and (8) are due to the intense
affinity which H2SO4 has for H2O. So thirsty is it that it even
abstracts H and O from oxalic acid in the right proportion to
form H2O, combines them, and then absorbs the water.

92. Affinity for Water.--This acid is a desiccator or dryer, and
is used to take moisture from the air and prevent metallic
substances from rusting. In this way it dilutes itself, and may
increase its weight threefold. In diluting, the acid must always
be poured into the water slowly and with stirring, not water into
the acid, since, as H2O is lighter than H2SO4, heat enough may be
set free at the surface of contact to cause an explosion.
Contraction also takes place, as may be shown by accurately
measuring each liquid in a graduate, before mixing, and again
when cold. The mixture occupies less volume than the sum of the
two volumes. For the best results the volume of the acid should
be about three times that of the water.
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