Familiar Letters on Chemistry by Justus Freiherr von Liebig
page 17 of 138 (12%)
page 17 of 138 (12%)
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diminution of their bulk takes place in a far greater degree as the
pressure increases. Again, if ammoniacal gas is reduced by a compressing force to one-sixth of its volume, or carbonic acid is reduced to one thirty-sixth, a portion of them loses entirely the form of a gas, and becomes a liquid, which, when the pressure is withdrawn, assumes again in an instant its gaseous state--another deviation from the law of Marriotte. Our process for reducing gases into fluids is of admirable simplicity. A simple bent tube, or a reduction of temperature by artificial means, have superseded the powerful compressing machines of the early experimenters. The cyanuret of mercury, when heated in an open glass tube, is resolved into cyanogen gas and metallic mercury; if this substance is heated in a tube hermetically sealed, the decomposition occurs as before, but the gas, unable to escape, and shut up in a space several hundred times smaller than it would occupy as gas under the ordinary atmospheric pressure, becomes a fluid in that part of the tube which is kept cool. When sulphuric acid is poured upon limestone in an open vessel, carbonic acid escapes with effervescence as a gas, but if the decomposition is effected in a strong, close, and suitable vessel of iron, we obtain the carbonic acid in the state of liquid. In this manner it may be obtained in considerable quantities, even many pounds weight. Carbonic acid is separated from other bodies with which it is combined as a fluid under a pressure of thirty-six |
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