The Story of Electricity by John Munro
page 28 of 181 (15%)
page 28 of 181 (15%)
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collects at the negative foil under the tube H. These facts can be
proved by dipping a red-hot wick or taper into the gas of the tube O and seeing it blaze in presence of the oxygen which feeds the combustion, then dipping the lighted taper into the gas of the tube H and watching it burn with the blue flame of hydrogen. The volume of gas at the CATHODE or negative electrode is always twice that at the ANODE or positive electrode, as it should be according to the known composition of water. Now, if we disconnect the battery and join the two platinum electrodes of the voltameter by a wire, we shall find a current flowing out of the voltameter as though it were a battery, but in the reverse direction to the original current which decomposed the water. This "secondary" or reacting current is evidently due to the polarisation of the foils--that is to say, the electro- positive and electro-negative gases collected on them. Professor Groves constructed a gas battery on this principle, the plates being of platinum and the two gases surrounding them oxygen and hydrogen, but the most useful development of it is the accumulator or storage battery. The first practicable secondary battery of Gaston Plante was made of sheet lead plates or electrodes, kept apart by linen cloth soaked in dilute sulphuric acid, after the manner of Volta's pile. It was "charged" by connecting the plates to a primary battery, and peroxide of lead (PbO2) was formed on one plate and spongy lead (Pb) on the other. When the charging current was cut off the peroxide plate became the positive and the spongy plate the negative pole of the secondary cell. |
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