The Story of Electricity by John Munro
page 32 of 181 (17%)
page 32 of 181 (17%)
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will get the united effect of the whole, and the total current
will flow through the wire W, joining the extreme bars or positive and negative poles of the battery. It must be borne in mind that although the bismuth and antimony of this thermo-electric battery, like the zinc and copper of the voltaic or chemico-electric battery, are respectively positive and negative to each other, the poles or wires attached to these metals are, on the contrary, negative and positive. This peculiarity arises from the current starting between the bismuth and antimony at the heated junction. The internal resistance of a "thermo-electric pile" is, of course, very slight, the metals being good conductors, and this fact gives it a certain advantage over the voltaic battery. Moreover, it is cleaner and less troublesome than the chemical battery, for it is only necessary to keep at the required difference of temperature between the hot and cold junctions in order to get a steady current. No solutions or salts are required, and there appears to be little or no waste of the metals. It is important, however, to avoid sudden heating and cooling of the joints, as this tends to destroy them. Clammond, Gulcher, and others have constructed useful thermo-piles for practical purposes. Figure 24 illustrates a Clammond thermo- pile of 75 couples or elements. The metals forming these pairs are an alloy of bismuth and antimony for one and iron for the other. Prisms of the alloy are cast on strips of iron to form the junctions. They are bent in rings, the junctions in a series making a zig-zag round the circle. The rings are built one over the other in a cylinder of couples, and the inner junctions are heated by a Bunsen gas-burner in the hollow core of the battery. A gas- |
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