Five of Maxwell's Papers by James Clerk Maxwell
page 24 of 51 (47%)
page 24 of 51 (47%)
![]() | ![]() |
|
of natural knowledge to one of those points at which we must accept
the guidance of that faith by which we understand that "that which is seen was not made of things which do appear." One of the most remarkable results of the progress of molecular science is the light it has thrown on the nature of irreversible processes--processes, that is, which always tend towards and never away from a certain limiting state. Thus, if two gases be put into the same vessel, they become mixed, and the mixture tends continually to become more uniform. If two unequally heated portions of the same gas are put into the vessel, something of the kind takes place, and the whole tends to become of the same temperature. If two unequally heated solid bodies be placed in contact, a continual approximation of both to an intermediate temperature takes place. In the case of the two gases, a separation may be effected by chemical means; but in the other two cases the former state of things cannot be restored by any natural process. In the case of the conduction or diffusion of heat the process is not only irreversible, but it involves the irreversible diminution of that part of the whole stock of thermal energy which is capable of being converted into mechanical work. This is Thomson's theory of the irreversible dissipation of energy, and it is equivalent to the doctrine of Clausius concerning the growth of what he calls Entropy. The irreversible character of this process is strikingly embodied in Fourier's theory of the conduction of heat, where the formulae |
|