Young's Demonstrative Translation of Scientific Secrets by Daniel Young
page 12 of 236 (05%)
page 12 of 236 (05%)
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chloride of barium to a small quantity of the washings, and when
there is no white precipitate formed by the test, the precipitate is sufficiently washed. A solution of cyanide of potassium is now added to this precipitate until it is dissolved, during which process the solution becomes warm by the chemical re-action which takes place. The solution is filtered, and allowed to repose all night. If the solution of cyanide of potassium that is used is strong, the greater portion of the ferrocyanide of potassium crystalises in the solution, and may be collected and preserved for use again. If the solution of cyanide of potassium used to dissolve the precipitate is dilute, it will be necessary to condense the liquor by evaporation to obtain the yellow prussiate in crystals. The remaining solution is the coppering solution; should it not be convenient to separate the yellow prussiate by crystallization, the presence of that salt in the solution does not deteriorate it nor interfere with its power of depositing copper. 19. PECULIARITIES IN WORKING CYANIDE OF COPPER SOLUTION The true composition of the salts thus formed by copper and cyanide of potassium has not yet been determined, but their relations to the battery and electrolyzation are peculiar. The solution must be worked at a heat not less than from 150 to 200 degrees Farenheit (that is not quite as hot a boiling water, which is 212 degrees Farenheit.) All other solutions we have tried follow the laws, that if the electricity is so strong as to cause gas to be evolved at the electrode, the metal will be deposited in a sandy or powdered state, but the solution of cyanide of copper and potassium is an exception to these laws, as there is no reguline deposit obtained |
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