Synthetic Tannins by Georg Grasser
page 18 of 193 (09%)
page 18 of 193 (09%)
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Dekker [Footnote: "De Looistoffen," vol. ii, p. 30 (1908).] was,
however, unable to detect diphenylmethane on distilling with zinc dust, and did, therefore, not accept Nierenstein's views. In proposing the formula-- O || HO ^ _ __C | | | | | }O | | | __OH | |____|_C_/ \OH HO V \__/ OH OH OH Dekker [Footnote: _Ber._, 1906, 34, 2497.] was enabled to account for most of the details in the behaviour of tannin, viz.: (1) the empirical constitution, C_14H_10O_9; (2) the almost complete hydrolysis into gallic acid (the dotted line indicates the decomposition of the molecule into 2 molecules gallic acid by taking up water); (3) the formation of diphenylmethane as a result of distillation with zinc dust; and (4) the electrical non-conductivity. Since tannin on acetylating yields a considerable amount of triacetylgallic acid, it should, according to Dekker, contain at least six acetylisable hydroxyls. Nierenstein [Footnote: _Chem. Ztg._, 1906, 31, 880.] objected to this formula on account of its containing seven hydroxyl groups, whereas Dekker found six, Nierenstein five, and Herzig still fewer hydroxyl groups. The formula would also favour the conception of tinctorial |
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