Acetylene, the Principles of Its Generation and Use by F. H. Leeds;W. J. Atkinson Butterfield
page 51 of 592 (08%)
page 51 of 592 (08%)
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hygroscopic, or greedy of moisture; so that if it is brought into the
presence of water, either in the form of liquid or as vapour, it immediately combines therewith to yield calcium hydroxide, or slaked lime, whose chemical formula is Ca(OH)_2. Accordingly, in actual practice, when calcium carbide is mixed with an excess of water, a secondary reaction takes place over and above that indicated by equation (1), the quicklime produced combining with one chemical part or molecule of water, thus-- CaO + H_2O = Ca(OH)_2. As these two actions occur simultaneously, it is more usual, and more in agreement with the phenomena of an acetylene generator, to represent the decomposition of calcium carbide by the combined equation-- (2) CaC_2 + 2H_2O = C_2H_2 + Ca(OH)_2. By the aid of calculations analogous to those employed in the preceding paragraph, it will be noticed that equation (2) states that 1 molecule of calcium carbide, or 64 parts by weight, combines with 2 molecules of water, or 36 parts by weight, to yield 1 molecule, or 26 parts by weight of acetylene, and 1 molecule, or 74 parts by weight of calcium hydroxide (slaked lime). Here again, if more than 36 parts of water are taken for every 64 parts of calcium carbide, the excess of water over those 36 parts is left undecomposed; and in the same fashion, if less than 36 parts of water are taken for every 64 parts of calcium carbide, some of the latter must remain unattacked, whilst, obviously, the amount of acetylene liberated cannot exceed that which corresponds with the quantity of substance suffering complete decomposition. If, for example, the quantity of water present in a generator is more than chemically |
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