Scientific American Supplement, No. 303, October 22, 1881 by Various
page 45 of 138 (32%)
page 45 of 138 (32%)
![]() | ![]() |
|
|
of precipitating the whole of gelatine with alcohol, and which would
take less time than the method of obtaining the bromide in a pure form. My first idea was to make up the solutions used in emulsifying in a very concentrated form, and, after emulsifying, boiling, and allowing to cool, to add to the thin emulsion thus obtained gelatine to the amount of twenty grains to the ounce, and to precipitate this with alcohol, the rest of the gelatine required to make up the bulk being afterwards added, and the whole thoroughly incorporated by warming and shaking. I was thus successful in reducing the amount of alcohol required to one-third of what would be necessary if the whole of the emulsion were precipitated; but still I found that, if a reliable emulsion were required, the pellicle as formed had to be washed to free it from the last trace of soluble salts. It now struck me that it might be possible to precipitate the bromide of silver direct from a very weak solution of gelatine, and obtain it in such a form that it might be filtered, washed, and in every way treated as an ordinary precipitate. I tried the following experiment. I took-- 1. Silver nitrate....................... 200 grains Water............................... 11/2 ounce. 2. Ammonia bromide...................... 120 grains. Water................................ 11/2 ounce. Gelatine............................. 12 grains. I emulsified the two together in the usual way, allowed the whole to cool, and then poured the thin emulsion into about ten ounces of alcohol, stirring the while. As I had anticipated, a flocculent precipitate was formed, which settled to the bottom of the vessel in a |
|


