Scientific American Supplement, No. 288, July 9, 1881 by Various
page 12 of 160 (07%)
page 12 of 160 (07%)
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into account at all. In the first place, hydrogen consumes only one
quarter as much oxygen as carbon, and, furthermore, two-ninths only of the heating power of hydrogen is used as the multiplying number, viz., 8,080, while the value of hydrogen is 34,462. In other words, one-eighteenth only of the available hydrogen present in the fuel is shown in the result obtained. Apart from this my experience of the working of Berthier's method has been by no means satisfactory. There is considerable difficulty in obtaining pure litharge, and it is almost impossible to procure a crucible which does not exert a reducing action upon the lead oxide. Some twelve months ago I went out to Italy to test a large number of cargoes of coal with Thompson's calorimeter, and since then this apparatus has superseded Berthier's process, and is likely to come into more general use. Like Berthier's method, Thompson's apparatus is not without its disadvantages, and the purpose of this paper is to set these forth, as well as to suggest a uniform method of working by means of which the great and irreconcilable differences in the results obtained by some chemists might be overcome. It has already been observed that a coal rich in hydrogen shows a low heating power by Berthier's method, and it will become evident on further reflection that the higher the percentage of carbon the greater will be the indicated calorific power. In fact a good sample of anthracite will give higher results than any other class of coal by Berthier's process. With Thompson's calorimeter the reverse is the case, as the whole of the heating power of the hydrogen is taken into account. In short, with careful working, the more bituminous a coal is the more certain is it that its full heating power shall be exerted and recorded, so far as the apparatus is capable of indicating it; for when the result obtained is multiplied by the equivalent of the latent heat of steam the product is always below the theoretical heat units calculated from the chemical composition of the coal by the acid of Favre and Silbermann's figures |
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