Scientific American Supplement, No. 288, July 9, 1881 by Various
page 17 of 160 (10%)
page 17 of 160 (10%)
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to bring it into calories, as is done by the authorities in Italy, makes
more than 100 heat units--a serious difference when 5d. per ton fine is attached to every 100 calories lower than the number guaranteed. Taking the latent heat of steam as 537 deg. C., and multiplying this number by 14.74, the evaporative power of the coal used in these experiments, its equivalent in calories is 7,915. From the analysis of this coal, disregarding the nitrogen and deducting an equivalent of hydrogen for the oxygen present, the _total heat units_ given by Favre and Silbermann's figures for carbon (8,080) and hydrogen (34,462) will be 8,746. It will be seen, therefore, that the calorific power, as determined by Thompson's apparatus, gives a much lower result when multiplied by 537 than the heat units calculated from the chemical composition of the coal. When I used Thompson's apparatus in the chemical laboratory at Turin to determine the evaporative power of various cargoes of South Wales coal, it was agreed by mutual consent that the temperature of the water at starting should be 39 deg. F. (the temperature at which the _heat unit_ was determined). The temperature of the room was about 60 deg., but this varied, as the weather was somewhat severe and changeable. Under these conditions, with the water at 39 deg. and room 60 deg., the coal which gives 14.74 lb. of water per lb. of coal, will give as high as 15.88 lb. of water per lb. of coal. This result multiplied by 537=8,496 calories, approaching much more nearly to the theoretic value. This method of working is still practiced abroad, but experience has shown that very widely differing results follow when working in this manner, especially if the temperature of the room is changeable, as it naturally is where ash determinations and other chemical work is proceeding simultaneously. The time the experiment lasts, taking the reading on a quickly rising thermometer and other considerations, render the experiments anything but trustworthy when |
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