Scientific American Supplement, No. 288, July 9, 1881 by Various
page 36 of 160 (22%)
page 36 of 160 (22%)
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any suitable receiver. The evolution of carbonic acid by this method is
rapid, but easily regulated, and the gas may be purified by causing it to pass through some water contained in another two-necked bottle, similar to the generator. The chemical change involved in this decomposition is expressed by the following equation: CaCO_3 + 2HCl = CO_2 + H_2O + CaCl_2 Calcium Hydrochloric Carbonic Water. Calcium Carbonate. Acid. Acid. Chloride. By referring to the table of combining weights given in a previous paper, it will be seen that 100 parts of calcium carbonate will yield 44 parts of carbonic acid. Instead of hydrochloric acid any other acid may be used, and in the practical manufacture of carbonic acid for aerated waters sulphuric acid is the one usually employed. Carbonic acid is colorless and inodorous, but has a peculiar sharp taste; it is half as heavy again as air, its exact specific gravity being 1529; one hundred cubic inches weigh 47.26 grains. It is uninflammable, and does not support combustion or animal respiration. Under a pressure of about 38 atmospheres, at a temperature of 32 deg. F., carbonic acid condenses into a colorless liquid, which may also be frozen into a compact mass resembling ice, or into a white powder like snow. Carbonic acid is soluble in water, and at the ordinary pressure and temperature one volume of water will hold in solution one volume of the gas; under increased pressures, far larger quantities of the gas can be held in solution, but this is rapidly evolved as soon as the excess of pressure is removed. Upon this property the manufacture of aerated waters depends. The presence of free carbonic acid can be easily detected by causing the gas to pass over the surface of some clear lime-water. If any be present a white film of carbonate of lime will at once be formed. |
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