Scientific American Supplement, No. 288, July 9, 1881 by Various
page 75 of 160 (46%)
page 75 of 160 (46%)
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mass from boiling water. The aqueous solution of the purified
crystalline scales then gave with ferric chloride only a small flesh-colored precipitate. The crystals melted at 120 deg. C. In order to demonstrate the presence of benzoic acid Herr Convert boiled the crystals with water and silver oxide and dried the scales that separated from the cooling filtrate over sulphuric acid. 0.0312 gramme gave upon combustion 0.0147 gramme of silver, or 47.1 per cent. The benzoate of silver contains 46.6 per cent, of metal; the crystals prepared from the acid of ilang-ilang oil were, therefore, benzoate of silver. For the separation of the alcoholic constituent, which is present in the form of an apparently not very considerable quantity of benzoic ether, far more ilang-ilang oil would be required than was at command. [Footnote 1: _Comptes Rendus_, lxxvi. (1873), 1428, and abstracted in the _Pharmaceutical Journal_ [3], iv., p. 28; also in _Jahresbericht_, 1873, p. 431.] [Footnote 2: Overlooking Peru balsam and Tolu balsam.] Besides the benzoic ether and, probably, a phenol, mentioned above, there may be recognized in ilang-ilang oil an aldehyde or ketone, inasmuch as upon shaking it with bisulphite of sodium I observed the formation of a very small quantity of crystals. That Gal did not obtain the like result must at present remain unexplained. Like the benzoic acid the acetic acid is, no doubt, present in cananga oil in the form of ether. * * * * * |
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