Scientific American Supplement, No. 401, September 8, 1883 by Various
page 22 of 136 (16%)
page 22 of 136 (16%)
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there is great tendency to frill--such, for instance, as when a soft
sample of gelatine has been employed, or old decomposed emulsion worked in with the fresh emulsion--it will in such cases be safer to put the plates in the normal-bath for a few minutes previous to immersing them in the acid bath. Potash alum is obtained tolerably pure in commerce in colorless transparent crystalline masses, having an acid, sweetish, astringent taste. It is soluble in 18 parts of water at 60 deg. F., and in its own weight of water at 212 deg. F.; but the excess crystallizes out upon cooling. The solution reddens litmus paper, and, when impure, usually contains traces of oxide of iron. Upon the addition of either caustic soda or potash, a white gelatinous precipitate is formed (hydrate of alumina), which is soluble in excess of the reagent employed. The precipitate thus obtained has much of the character of the opalescent film sometimes observed on gelatine plates, when dry, which have been soaked in alum, and not well washed afterward. Alkaline carbonates--such as washing soda, for instance--precipitate hydrate of alumina, which does not dissolve in an excess of the reagents, and carbon dioxide is evolved. Ammonia hydrate produces a precipitate in a much finer state of divison, which does not dissolve in excess when examined in a test-tube, it somewhat resembles thin starch paste. The presence of traces of iron may be known by adding a few drops of hydrochloric acid to a small quantity of a saturated solution of alum in a test-tube, to which add strong liquid ammonia; should any iron be present, the mixture will have a reddish-brown tinge when examined over |
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