Scientific American Supplement, No. 401, September 8, 1883 by Various
page 29 of 136 (21%)
page 29 of 136 (21%)
|
containing in aqueous solution such decolorizing agents as the
hypochlorites in general, and chlorides, bromides, and iodides that are capable of disengaging chlorine, and iodine or an iodide in a nascent state. These gases perform the role of oxidizing or decolorizing agents. The fibers that are immersed in the solution during the passage of the electric current must necessarily remain therein for a greater or less length of time, according to the nature of the material to be bleached, and must, after this first operation, be washed, rinsed, and dried. The use of an electric current for decomposing the metallic chlorides and disengaging their elements is not new, and there have been specially utilized for this purpose, up to the present time, the alkaline hypochlorites that are obtained by well known processes. In the latter case the metal is brought to the state of oxide in presence of the water that is necessary for the reaction. But the results obtained in practicing this method are deceiving, as far as bleaching is concerned, and it is evidently more rational and economical to endeavor to compound the hypochlorite directly by borrowing all its elements from the metallic chloride itself, and from the water by means of which such transformation is to be effected. This is a reversal of the problem, and, _a propos_ thereof, we would call the attention of the reader to an apparatus invented by Messrs. Naudin & Schneider for effecting such synthesis in a simple and practical manner. If a solution of chloride of sodium or kitchen salt, NaCl, be submitted to electrolysis in a hermetically closed vessel containing the material to be bleached, a formation of hypochlorite of soda is produced in the following way: |
|