Scientific American Supplement, No. 384, May 12, 1883 by Various
page 74 of 136 (54%)
page 74 of 136 (54%)
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It will be observed that we keep the bromide in excess while mixing. I
must not forget to mention that to those experienced in mixing, by far the best method is that described by Captain Abney in his Cantor lectures, of keeping the silver in excess. The emulsion, being properly mixed, has now to be placed in the water bath, and kept at the boiling point for forty-five minutes. As, obviously, I cannot keep you waiting while this is done, I propose to divide our emulsion into two portions, allowing one portion to stew, and to proceed with the next operation with the remainder. Supposing, then, this emulsion has been boiled, it is placed in cold water to cool. While it is cooling, let us consider for a moment what takes place during the boiling. It is found that during this time the emulsion undergoes two remarkable changes: 1. The molecules of silver bromide gradually aggregate together, forming larger and larger particles. 2. The emulsion increases rapidly in sensitiveness. Now what is the cause, in the first place, of this aggregation of molecules: and, in the second place, of the increase of sensitiveness? We know that the two invariably go together, so that we are right in concluding that the same cause produces both. It might be thought that heat is the cause, but the same changes take place more slowly in the cold, so we can only say that heat accelerates the action, and hence must conclude that the prime cause is one of the materials in the emulsion itself. |
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