Scientific American Supplement, No. 385, May 19, 1883 by Various
page 109 of 130 (83%)
page 109 of 130 (83%)
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These colors are not suitable for converting white wine into red, but
they can be used for giving wines a faint red tint, for darkening pale red wines, and in making up a factitious bouquet essence, which is added to red wines. The most suitable methods for the detection of magenta are those given by Romei and Falieres-Ritter. If a wine colored with archil and one colored with cudbear are treated treated according to Romei's method, the former gives, with basic lead acetate, a blue, and the latter a fine violet precipitate. The filtrate, if shaken up with amylic alcohol, gives it in either case a red color. A knowledge of this fact is important, or it may be mistaken for magenta. The behavior of the amylic alcohol, thus colored red, with hydrochloric acid and ammonia is characteristic. If the red color is due to magenta, it is destroyed by both these reagents, while hydrocholoric acid does not decolorize the solutions of archil and cudbear, and ammonia turns their red color to a purple violet. If the wine is examined according to the Falieres-Ritter method in presence of magenta, ether, when shaken up with the wine, previously rendered ammoniacal, remains colorless, while if archil or cudbear is present the ether is colored red. Wartha has made a convenient modification in the Falieres-Ritter method by adding ammonia and ether to the concentrated wine while still warm. If the red color of the wool is due to archil or cudbear, it is extracted by hydrochloric acid, which is colored red. Ammonia turns the color to a purple violet. Koenig mixed 50 c.c. wine with ammonia in slight excess, and places in the mixture about one-half grm. clean white woolen yarn. The whole is then boiled in a flask until all the alcohol and the excess of ammonia are driven off. The wool taken out of the liquid and purified by washing in water and wringing is moistened in a test-tube with pure potassa lye at 10 per cent. It is carefully heated till the wool is completely dissolved, and the solution, when cold, is mixed first with half its volume of pure alcohol, upon which is carefully poured the same volume |
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