Scientific American Supplement, No. 385, May 19, 1883 by Various
page 37 of 130 (28%)
page 37 of 130 (28%)
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a small model whose external dimensions are 160 x 100 x 90 millimeters.
"My invention," says the inventor, "is intended as an electric pile capable of regeneration. The annexed Fig. 1 shows a vertical arrangement of the apparatus, and Fig. 2 a horizontal one. In the latter, two elements are represented superposed. "My pile consists of a prism of retort carbon (a) covered on every side with pure chloride of silver (b). The carbon thus prepared is immersed in a solution of hydrate of potassium (KHO) or of hydrate of sodium (NaHO), marking 1.30 to 1.45 by the Baume areometer, the solvent being water. "In the vicinity of the carbon is arranged the plate to be attacked--a plate of zinc (c) of good quality. The surface of the electrodes, and their distance apart, depends upon the effects that it is desired to obtain, and is determined in accordance with the well known principles of electro-kinetics. "The chemical reactions that take place in this couple are multiple. In contact with a sufficiently concentrated solution of hydrate of potassium or sodium, the chloride of silver, especially if it has been recently prepared, passes partially into the state of brown or black oxide, so that the carbon becomes covered, after remaining sufficiently long in the exciting liquid, with a mixture of chloride and oxide of silver. When the circuit is closed, the chloride becomes reduced to a spongy metallic state and adheres to the surface of the carbon. At the same time the zinc passes, in the alkaline solution, into a state of chloride and of soluble combination of zinc oxide and of alkali. |
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