Scientific American, Volume 17, No. 26 December 28, 1867 - A Weekly Journal of Practical Information, Art, Science, Mechanics, Chemistry, and Manufactures. by Various
page 6 of 202 (02%)
page 6 of 202 (02%)
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freezes at about 46; it is made to decompose in a very peculiar way; on
moistening paper with it it burns with rapidity; it does not explode when red-hot copper is placed in it; we tried it with the most intense heat--we can produce with a galvanic battery with two hundred cells holding a gallon and a half each; some nitro-glycerin was placed in a cup and connected with one of the poles of the battery; through a pencil of gas carbon the other poles of the battery were connected with the glycerin, no explosion ensued; but when the point touched the britannia vessel the nitro-glycerin took fire, a portion burning and the rest scattering about; this is as severe a test as we can submit it to in the way of heat under the pressure of the air; we therefore would conclude that nitro-glycerin carried about exposed cannot explode, even if you drop a coal of fire into it; if the liquid is confined, or is under pressure, then an explosion will ensue; if paper be moistened with it and put on an anvil and a smart blow given with a hammer, a sharp detonation ensues; if gunpowder or the fulminates of mercury, silver or gun-cotton be ignited in a vacuum by a galvanic battery, none of them will explode; if any gas be introduced so as to produce a gentle pressure during the decomposition, then a rapid evolution of gases will result; the results of decomposition in a vacuum differ from those under atmospheric pressure or when they are burnt in a pistol, musket, a cannon, or in a mine; where we have little or no pressure it is difficult to get these substances to burn rapidly; nitro-glycerin is more difficult to explode than powder; in many respects it resembles gun-cotton which is made in a similar way; if gun-cotton be immersed in the proto-chloride of iron it turns into common cotton; the same experiment was tried with nitro-glycerin by mixing it with proto-chloride of iron, and it reverted into common glycerin; there are four well known varieties of gun-cotton made by employing acids of different strengths; they differ in chemical composition and properties, |
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