Popular Science Monthly - Oct, Nov, Dec, 1915 — Volume 86 by Anonymous
page 192 of 485 (39%)
page 192 of 485 (39%)
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Volta reaches a similar conclusion after repeating some of Bennett's experiments. In referring to this decision of Volta as to the origin of the electric charge in contact electrification, Ostwald says: 'We stand here at a point where the most prolific error of Electrochemistry begins, the combating of which has from that time on occupied almost the greater part of the scientific work in this field.' The error, from Ostwald's point of view, lies in the assumption that the transference of electricity from the one metal to the other is a primary phenomenon of metallic contact. He, with many others, including some of the most distinguished physicists and chemists of the past century, regard the electrical transference as a secondary phenomenon resulting from the previous oxidation of one of the metals. Thus Lodge, in discussing the opposite electrification of plates of zinc and copper when brought into contact says: 'The effective cause of the whole phenomenon in either case is the greater affinity of oxygen for zinc rather than copper.' The apparent conflict of opinion between those who hold that the different affinities of the metals for oxygen is the cause of the rearrangement of their electrical charges when brought into contact and those who hold with Bennett and Cavallo that the metals in their natural state have different affinities for the electrical fluid must disappear when we recognize that all |
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