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An Introductory Course of Quantitative Chemical Analysis - With Explanatory Notes by Henry P. Talbot
page 30 of 272 (11%)
consider the cubic centimeter to be one one-thousandth of that volume.
The true liter is the volume of 1000 grams of water at 4°C.; but
this is obviously a lower temperature than that commonly found in
laboratories, and involves the constant use of corrections if taken as
a laboratory standard. Many laboratories use 15.5°C. (60° F.) as the
working standard. It is plain that any temperature which is deemed
most convenient might be chosen for a particular laboratory, but it
cannot be too strongly emphasized that all measuring instruments,
including burettes, pipettes, and flasks, should be calibrated at that
temperature in order that the contents of each burette, pipette,
etc., shall be comparable with that of every other instrument, thus
permitting general interchange and substitution. For example, it is
obvious that if it is desired to remove exactly 50 cc. from a solution
which has been diluted to 500 cc. in a graduated flask, the 50 cc.
flask or pipette used to remove the fractional portion must give
a correct reading at the same temperature as the 500 cc. flask.
Similarly, a burette used for the titration of the 50 cc. of solution
removed should be calibrated under the same conditions as the
measuring flasks or pipettes employed with it.

The student should also keep constantly in mind the fact that all
volumetric operations, to be exact, should be carried out as nearly at
a constant temperature as is practicable. The spot selected for
such work should therefore be subject to a minimum of temperature
variations, and should have as nearly the average temperature of
the laboratory as is possible. In all work, whether of calibration,
standardization, or analysis, the temperature of the liquids employed
must be taken into account, and if the temperature of these liquids
varies more than 3° or 4° from the standard temperature chosen for the
laboratory, corrections must be applied for errors due to expansion or
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