Book-bot.com - read famous books online for free

An Introductory Course of Quantitative Chemical Analysis - With Explanatory Notes by Henry P. Talbot
page 32 of 272 (11%)

The differences in readings represent the apparent volumes, the
differences in weights the true volumes. For example, if an apparent
volume of 10.05 cc. is found to weigh 10.03 grams, it may be assumed
with sufficient accuracy that the error in that 10 cc. amounts to
-0.02 cc., or -0.002 for each cubic centimeter (Note 3).

In the calculation of corrections the temperature of the water must be
taken into account, if this varies more than 4°C. from the laboratory
standard temperature, consulting the table of densities of water in
the Appendix.

From the final data, plot the corrections to be applied so that they
may be easily read for each cubic centimeter throughout the burette.
The total correction at each 10 cc. may also be written on the burette
with a diamond, or etching ink, for permanence of record.

[Note 1: A small quantity of liquid at first adheres to the side of
even a clean burette. This slowly unites with the main body of liquid,
but requires an appreciable time. Three minutes is a sufficient
interval, but not too long, and should be adopted in every instance
throughout the whole volumetric practice before final readings are
recorded.]

[Note 2: A comparatively rough balance, capable of weighing to
centigrams, is sufficiently accurate for use in calibrations, for a
moment's reflection will show that it would be useless to weigh the
water with an accuracy greater than that of the readings taken on
the burette. The latter cannot exceed 0.01 cc. in accuracy, which
corresponds to 0.01 gram.
DigitalOcean Referral Badge