An Introductory Course of Quantitative Chemical Analysis - With Explanatory Notes by Henry P. Talbot
page 32 of 272 (11%)
page 32 of 272 (11%)
|
The differences in readings represent the apparent volumes, the differences in weights the true volumes. For example, if an apparent volume of 10.05 cc. is found to weigh 10.03 grams, it may be assumed with sufficient accuracy that the error in that 10 cc. amounts to -0.02 cc., or -0.002 for each cubic centimeter (Note 3). In the calculation of corrections the temperature of the water must be taken into account, if this varies more than 4°C. from the laboratory standard temperature, consulting the table of densities of water in the Appendix. From the final data, plot the corrections to be applied so that they may be easily read for each cubic centimeter throughout the burette. The total correction at each 10 cc. may also be written on the burette with a diamond, or etching ink, for permanence of record. [Note 1: A small quantity of liquid at first adheres to the side of even a clean burette. This slowly unites with the main body of liquid, but requires an appreciable time. Three minutes is a sufficient interval, but not too long, and should be adopted in every instance throughout the whole volumetric practice before final readings are recorded.] [Note 2: A comparatively rough balance, capable of weighing to centigrams, is sufficiently accurate for use in calibrations, for a moment's reflection will show that it would be useless to weigh the water with an accuracy greater than that of the readings taken on the burette. The latter cannot exceed 0.01 cc. in accuracy, which corresponds to 0.01 gram. |
|