An Introductory Course of Quantitative Chemical Analysis - With Explanatory Notes by Henry P. Talbot
page 42 of 272 (15%)
page 42 of 272 (15%)
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A !normal acid solution! should contain in one liter that quantity of
the reagent which represents 1 gram of hydrogen replaceable by a base. For example, the normal solution of hydrochloric acid (HCl) should contain 36.46 grams of gaseous hydrogen chloride, since that amount furnishes the requisite 1 gram of replaceable hydrogen. On the other hand, the normal solution of sulphuric acid (H_{2}SO_{4}) should contain only 49.03 grams, i.e., one half of its molecular weight in grams. A !normal alkali solution! should contain sufficient alkali in a liter to replace 1 gram of hydrogen in an acid. This quantity is represented by the molecular weight in grams (40.01) of sodium hydroxide (NaOH), while a sodium carbonate solution (Na_{2}CO_{3}) should contain but one half the molecular weight in grams (i.e., 53.0 grams) in a liter of normal solution. Half-normal or tenth-normal solutions are employed in most analyses (except in the case of the less soluble barium hydroxide). Solutions of the latter strength yield more accurate results when small percentages of acid or alkali are to be determined. INDICATORS It has already been pointed out that the purpose of an indicator is to mark (usually by a change of color) the point at which just enough of the titrating solution has been added to complete the chemical change which it is intended to bring about. In the neutralization processes which are employed in the measurement of alkalies (!alkalimetry!) or acids (!acidimetry!) the end-point of the reaction should, in |
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