Scientific American Supplement, No. 832, December 12, 1891 by Various
page 114 of 147 (77%)
page 114 of 147 (77%)
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fluorine.
Moreover, the hydrofluoric acid is found to contain a small quantity of platinum fluoride in solution. The electrolytic reaction is probably therefore much more complicated than was at first considered to be the case. The mixture of acid and alkaline fluoride furnishes fluorine at the positive terminal rod, but this intensely active gas, in its nascent state, attacks the platinum and produces platinum tetrafluoride, PtF_{4}; this probably unites with the potassium fluoride to form a double salt, possibly 2Kl.PtF_{4}, analogous to the well known platinochloride 2KCl.PtCl_{4}; and it is only when the liquid contains this double salt that the electrolysis proceeds in a regular manner, yielding free fluorine at the positive pole, and hydrogen and the complex black compound at the negative pole. PHYSICAL PROPERTIES OF FLUORINE. Fluorine possesses an odor which M. Moissan compares to a mixture of hypochlorous acid and nitrogen peroxide, but this odor is usually masked by that of the ozone which it always produces in moist air, owing to its decomposition of the water vapor. It produces most serious irritation of the bronchial tubes and mucous membrane of the nasal cavities, the effects of which are persistent for quite a fortnight. When examined in a thickness of one meter, it is seen to possess a greenish yellow color, but paler, and containing more of yellow, than that of chlorine. In such a layer, fluorine does not present any absorption bands. Its spectrum exhibits thirteen bright, lines in the |
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