Scientific American Supplement, No. 832, December 12, 1891 by Various
page 120 of 147 (81%)
page 120 of 147 (81%)
![]() | ![]() |
|
liquid fluoride of iodine attacks glass with great energy and
decomposes water when dropped into that liquid with a noise like that produced by red-hot iron. Its properties agree with those of the fluoride of iodine prepared by Gore by the action of iodine on silver fluoride. _Phosphorus._--Immediately phosphorus, either the ordinary yellow variety or red phosphorus, comes in contact with fluorine, a most lively action occurs, accompanied by vivid incandescence. If the fluorine is in excess, a fuming gas is evolved, which gives up its excess of fluorine on collecting over mercury, and is soluble in water. This gas is phosphorus pentafluoride, PF_{5}, prepared some years ago by Prof. Thorpe. If, on the contrary, the phosphorus is in excess, a gaseous mixture of this pentafluoride with a new fluoride, the trifluoride, PF_{3}, a gas insoluble in water, but which may be absorbed by caustic potash, is obtained. The trifluoride, in turn, combines with more fluorine to form the pentafluoride, the reaction being accompanied by the appearance of a flame of comparatively low temperature. _Arsenic_ combines with fluorine at the ordinary temperature with incandescence. If the current of fluorine is fairly rapid, a colorless fuming liquid condenses in the receiver, which is mainly arsenic trifluoride, AsF_{3}, but which appears also to contain a new fluoride, the pentafluoride, AsF_{5}, inasmuch as the solution in water yields the reactions of both arsenious and arsenic acids. _Carbon._--Chlorine does not unite with carbon even at the high temperature of the electric arc, but fluorine reacts even at the ordinary temperature with finely divided carbon. Purified lampblack |
|