Scientific American Supplement, No. 832, December 12, 1891 by Various
page 121 of 147 (82%)
page 121 of 147 (82%)
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inflames instantly with great brilliancy, as do also the lighter
varieties of wood charcoal. A curious phenomenon is noticed with wood charcoal; it appears at first to absorb and condense the fluorine, then quite suddenly it bursts into flame with bright scintillations. The denser varieties of charcoal require warming to 50° or 60° before they inflame, but it once the combustion is started at any point it rapidly propagates itself throughout the entire piece. Graphite must be heated to just below dull redness in order to effect combination; while the diamond has not yet been attacked by fluorine, even at the temperature of the Bunsen flame. A mixture of gaseous fluorides of carbon are produced whenever carbon of any variety is acted upon by fluorine, the predominating constituent being the tetrafluoride, CF_{4}. _Boron._--The amorphous variety of boron inflames instantly in fluorine, with projection of brilliant sparks and liberation of dense fumes of boron trifluoride, BF_{3}. The adamantine modification behaves similarly if powdered. When the experiment is performed in the fluorspar tube, the gaseous fluoride may be collected over mercury. The gas fumes strongly in the air, and is instantly decomposed by water. _Silicon._--The reaction between fluorine and silicon is one of the most beautiful of all these extraordinary manifestations of chemical activity. The cold crystals become immediately white-hot, and the silicon burns with a very hot flame, scattering showers of star-like, white-hot particles in all directions. If the action is stopped before all the silicon is consumed, the residue is found to be fused. As crystalline silicon only melts at a temperature superior to 1,200°, the heat evolved must be very great. If the reaction is performed in |
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