Scientific American Supplement, No. 832, December 12, 1891 by Various
page 122 of 147 (82%)
page 122 of 147 (82%)
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the fluorspar tube, the resulting gaseous silicon tetrafluoride,
SiF_{4}, may be collected over mercury. Amorphous silicon likewise burns with great energy in fluorine. ACTION OF FLUORINE UPON METALS. _Sodium_ and _potassium_ combine with fluorine with great vigor at ordinary temperatures, becoming incandescent, and forming their respective fluorides, which may be obtained crystallized from water in cubes. Metallic _calcium_ also burns in fluorine gas, forming the fused fluoride, and occasionally minute crystals of fluorspar. _Thallium_ is rapidly converted to fluoride at ordinary temperatures, the temperature rising until the metal melts and finally becomes red hot. Powdered _magnesium_ burns with great brilliancy. _Iron_, reduced by hydrogen, combines in the cold with immediate incandescence, and formation of an anhydrous, readily soluble, white fluoride. _Aluminum_, on heating to low redness, gives a very beautiful luminosity, as do also _chromium_ and _manganese_. The combustion of slightly warmed zinc in fluorine is particularly pretty as an experiment, the flame being of a most dazzling whiteness. _Antimony_ takes fire at the ordinary temperature, and forms a solid white fluoride. _Lead_ and _mercury_ are attacked in the cold, as previously described, the latter with great rapidity. _Copper_ reacts at low redness, but in a strangely feeble manner, and the white fumes formed appear to combine with a further quantity of fluorine to form a perfluoride. The main product is a volatile white fluoride. _Silver_ is only slowly attacked in the cold. When heated, however, to 100°, the metal commences to be covered with a yellow coat of anhydrous |
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