Scientific American Supplement, No. 832, December 12, 1891 by Various
page 123 of 147 (83%)
page 123 of 147 (83%)
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fluoride, and on heating to low redness combination occurs, with
incandescence, and the resulting fluoride becomes fused, and afterward presents a satin-like aspect. _Gold_ becomes converted into a yellow deliquescent volatile fluoride when heated to low redness, and at a slightly higher temperature the fluoride is dissociated into metallic gold and fluorine gas. The action of fluorine on _platinum_ has been studied with special care. It is evident, in view of the corrosion of the positive platinum terminal of the electrolysis apparatus, that nascent fluorine rapidly attacks platinum at a temperature of -23°. At 100°, however, fluorine gas appears to be without action on platinum. At 500°-600° it is attacked strongly, with formation of the tetrafluoride. PtF_{4}, and a small quantity of the protofluoride, PtF_{2}. If the fluorine is admixed with vapor of hydrofluoric acid, the reaction is much more vigorous, as if a fluorhydrate of the tetrafluoride, perhaps 2HF.PtF_{4}, were formed. The tetrafluoride is generally found in the form of deep-red fused masses, or small yellow crystals resembling those of anhydrous platinum chloride. The salt is volatile and very hygroscopic. Its behavior with water is peculiar. With a small quantity of water a brownish yellow solution is formed, which, however, in a very short time becomes warm and the fluoride decomposes; platinic hydrate is precipitated, and free hydrofluoric acid remains in solution. If the quantity of water is greater, the solution may be preserved for some minutes without decomposition. If the liquid is boiled, it decomposes instantly. At a red heat platinic fluoride decomposes into metallic platinum and fluorine, which is evolved in the free state. This reaction can therefore be employed as a ready means of preparing fluorine, the fluoride only requiring to be heated rapidly to redness in a platinum tube closed at one end, when |
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