Scientific American Supplement, No. 832, December 12, 1891 by Various
page 125 of 147 (85%)
page 125 of 147 (85%)
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their respective fluorides. When fluorine is delivered into an aqueous
solution of hydriodic acid, each bubble as it enters produces a flash of flame, and if the fluorine is being evolved fairly rapidly there is a series of very violent detonations. A curious reaction also occurs when fluorine is similarly passed into a 50 per cent. aqueous solution of hydrofluoric acid itself, a flame being produced in the middle of the liquid, accompanied by a series of detonations. _Nitric acid_ vapor reacts with great violence with fluorine, a loud explosion resulting. If fluorine is passed into the ordinary liquid acid, each bubble as it enters produces a flame in the liquid. _Ammonia gas_ is decomposed by fluorine with formation of a yellow flame, forming hydrofluoric acid and liberating nitrogen. With a solution of the gas in water, each bubble of fluorine produces an explosion and flame, as in case of hydriodic acid. _Phosphoric anhydride_, when heated to low redness, burns with a pale flame in fluorine, forming a gaseous mixture of fluorides and oxyfluoride of phosphorus. _Pentachloride and trichloride of phosphorus_ both react most energetically with fluorine, instantly producing a brilliant flame, and evolving a mixture of phosphorus pentafluoride and free chlorine. _Arsenious anhydride_ also affords a brilliant combustion, forming the liquid trifluoride of arsenic, AsF_{3}. This liquid in turn appears to react with more fluorine with considerable evolution of heat, probably forming the pentafluoride, AsF_{5}. _Chloride of arsenic_, AsCl_{3}, is converted with considerable energy to the trifluoride, free chlorine being liberated. |
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