Scientific American Supplement, No. 832, December 12, 1891 by Various
page 126 of 147 (85%)
page 126 of 147 (85%)
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_Carbon bisulphide_ inflames in the cold in contact with fluorine, and if the fluorine is led into the midst of the liquid a similar production of flame occurs under the surface of the liquid, as in case of nitric acid. No carbon is deposited, both the carbon and sulphur being entirely converted into gaseous fluorides. _Carbon tetrachloride_, as previously mentioned, reacts only very slowly with fluorine. The liquid may be saturated with gaseous fluorine at 15°, but on boiling this liquid a gaseous mixture is evolved, one constituent of which is carbon tetrafluoride, CF_{4}, a gas readily capable of absorption by alcoholic potash. The remainder consists of another fluoride of carbon, incapable of absorption by potash and chlorine. A mixture of the vapors of carbon tetrachloride and fluorine inflames spontaneously with detonation, and chlorine is liberated without deposition of carbon. _Boric anhydride_ is raised to a most vivid incandescence by fluorine, the experiment being rendered very beautiful by the abundant white fumes of the trifluoride which are liberated. _Silicon dioxide_, one of the most inert of substances at the ordinary temperature, takes fire in the cold in contact with fluorine, becoming instantly white-hot, and rapidly disappearing in the form of silicon tetrafluoride. The _chlorides_ of both _boron_ and _silicon_ are decomposed by fluorine, with formation of fluorides and liberation of chlorine, the reaction being accompanied by the production of flame. ACTION OF FLUORINE UPON METALLIC COMPOUNDS. |
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