Scientific American Supplement, No. 832, December 12, 1891 by Various
page 127 of 147 (86%)
page 127 of 147 (86%)
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_Chlorides_ of the metals are instantly decomposed by fluorine, generally at the ordinary temperature, and in certain cases, antimony trichloride for instance, with the appearance of flame. Chlorine is in each case liberated, and a fluoride of the metal formed. A few require heating, when a similar decomposition occurs, often accompanied by incandescence, as in case of chromium sesquichloride. _Bromides_ and _iodides_ are decomposed with even greater energy, and the liberated bromine and iodine burn in the fluorine with formation of their respective fluorides. _Cyanides_ react in a most beautiful manner with fluorine, the displaced cyanogen burning with a purple flame. Potassium ferrocyanide in particular affords a very pretty experiment, and reacts in the cold. Ordinary potassium cyanide requires slightly warming in order to start the combustion. Fused _potash_ yields potassium fluoride and ozone. Aqueous potash does not form potassium hypofluorite when fluorine is bubbled into it, but only potassium fluoride. _Lime_ becomes most brilliantly incandescent, owing partly to the excess being raised to a very high temperature by the heat developed during the decomposition, and partly to the phosphorescence of the calcium fluoride formed. _Sulphides_ of the alkalies and alkaline earths are also immediately rendered incandescent, fluorides of the metal and sulphur being respectively formed. _Boron nitride_ behaves in an exceedingly beautiful manner, being |
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