Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 28 of 352 (07%)
page 28 of 352 (07%)
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to heat, and even when quite pure will not stand a temperature of 100° C.
for a longer period than a few hours, without undergoing decomposition. Up to a temperature of 45° C., however, properly made and purified nitro- glycerine will remain unchanged almost indefinitely. The percentage composition of nitroglycerine is as follows:-- Found. Theory for C_{3}H_{5}(N0_{2})_{3}. Carbon 15.62 15.86 per cent. Hydrogen 2.40 2.20 " Nitrogen 17.90 18.50 " Oxygen ... 63.44 " The above analysis is by Beckerheim. Sauer and Adou give the nitrogen as 18.35 to 10.54 per cent. by Dumas' method; but I have never found any difficulty in obtaining percentages as high as 18.46 by the use of Lunge's nitrometer. The decomposition products by explosion are shown by the following equation-- 2C_{3}H_{5}(NO_{3})_{3} = 6CO_{2} + 5H_{2}O + 6N + O; that is, it contains an excess of 3.52 per cent. of oxygen above that required for complete combustion; 100 grms. would be converted into-- Carbonic Acid (CO_{2}) 58.15 per cent. Water 19.83 " Oxygen 3.52 per cent. Nitrogen 18.50 " The volume of gases produced at 0° and 760 mm., calculated from the above, |
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