Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 29 of 352 (08%)
page 29 of 352 (08%)
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is 714 litres per kilo, the water being taken as gaseous. Nitro-glycerine
is decomposed differently if it is ignited as dynamite (i.e., kieselguhr dynamite), and if the gases are allowed to escape freely under a pressure nearly equal to that of the atmosphere. Sarrau and Vieille obtained under these conditions, for 100 volumes of gas-- NO 48.2 per cent. CO 35.9 " CO_{2} 12.7 " H 1.6 per cent. N 1.3 " CH_{4} 0.3 " These conditions are similar to those under which a mining charge, simply ignited by the cap, burns away slowly under a low pressure (i.e., a miss fire). In a recent communication, P.F. Chalon (_Engineering and Mining Journal_, 1892) says, that in practice nitro-glycerine vapour, carbon monoxide, and nitrous oxide, are also produced as the result of detonation, but he attributes their formation to the use of a too feeble detonator. Nitro-glycerine explodes very violently by concussion. It may be burned in an open vessel, but if heated above 250° C. it explodes. Professor C.E. Munroe gives the firing point as 2O3°-2O5° C., and L. de Bruyn[A] states its boiling point as 185°. He used the apparatus devised by Horsley. The heat of formation of nitro-glycerine, as deduced from the heat of combustion by M. Longuinine, is 432 calories for 1 grm.; and the heat of combustion equals 1,576 cals. for 1 grm. In the case of nitro-glycerine the heat of total combustion and the heat of complete decomposition are interchangeable terms, since it contains an excess of oxygen. According to |
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