Nitro-Explosives: A Practical Treatise by P. Gerald Sanford
page 30 of 352 (08%)
page 30 of 352 (08%)
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Dr W.H. Perkin, F.R.S.,[B] the magnetic rotation of nitro-gylcerine is
5,407, and that of tri-methylene nitrate, 4.769 (diff. = .638). Dr Perkin says: "Had nitro-glycerine contained its nitrogen in any other combination with oxygen than as -O-NO_{2}, as it might if its constitution had been represented as C_{3}H_{2}(NO_{2})_{3}(OH)_{3}, the rotation when compared with propyl nitrate (4.085) would be abnormal." [Footnote A: _Jour. Soc. Chem. Ind._, June 1896, p. 471.] [Footnote B: _Jour. Chem. Soc._, W.H. Perkin, 1889, p. 726.] The solubility of nitro-glycerine in various solvents has been investigated by A.H. Elliot; his results may be summarised as follows:-- _______________________________________________________________________ | | Solvent. | Cold. | Warm. _____________________________|______________________|__________________ | | Water | Insoluble | Slightly soluble Alcohol, absolute | Soluble | Soluble " 93% | " | " " 80% | Slowly soluble | " " 50% | Insoluble | Slightly soluble Methyl alcohol | Soluble | Soluble Amyl " | " | " Ether, ethylic | " | " " acetic | " | " Chloroform | " | " Acetone | " | " |
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