A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 37 of 359 (10%)
page 37 of 359 (10%)
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when fused with them; therefore, it not only directly combines with
oxides, but it expels, by fusion, all other volatile acids from their salts. Furthermore, boracic acid promotes the oxidation of metals and sulphur, and induces haloid compounds, in the oxidation flame, to combine with the rising oxides. Borates thus made, melt generally by themselves; but admixed with borate of soda, they fuse much more readily, give a clear bead. Borax acts either as a flux, or through the formation of double salts. In borax, we have the action of free boracic acid, as well as borate of soda, and for that reason it is an excellent reagent for blowpipe analysis. All experiments in which borax is employed should be effected upon platinum wire. The hook of the wire should be heated red hot, and then dipped into the powdered borax. This should be exposed to the oxidation flame, when it will be fused to a bead, which adheres to the hook. This should be then dipped into the powdered substance, which will adhere to it if it is hot; but if the bead is cool, it must be previously moistened. Expose this bead to the oxidation flame until it ceases to change, then allow it to cool, when it should be exposed to the reduction flame. Look for the following in the oxidation flame: (1.) Whether the heated substance is fused to a clear bead or not, and whether the bead remains transparent after cooling. The beads of some substances, for instance those of the alkaline earths, are clear while hot; but upon cooling, are milk-white and enamelled. Some substances give a clear bead when heated and when cold, but appear enamelled when heated intermittingly or with a flame which changes often from oxidation to reduction, or with an |
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